Never Step on a Scorpion/Sands of Crime
S01E05 - Airdate: 1967-10-07
Runtime: 30 min
J. Jonah Jameson commissions the creation of the Scorpion to hunt down Spider-Man, but gets more than he bargained for when the Scorpion turns his sights on him. Spider-Man is framed for the theft of the Goliath Diamond and must track down the real criminal, the shape-shifting Sandman.
Episode details and rating from TVmaze.