Star Trek: The Animated Series
The Magicks of Megas-Tu
S01E08 - Airdate: 1973-10-27
Runtime: 30 min
The Enterprise travels to the center of the galaxy only to discover themselves sucked into a dimension where the laws of time and space no longer apply, and "magic" functions for those capable of grasping its fundamentals. Stopping at Megas-Tu, a planet where magic and witchcraft are the norm, the crew finds their guide is Lucien, who is Lucifer of Earth mythology.
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Episode details and rating from TVmaze.